Introduction Chevron Phillips Chemical Company is the major producer of Cyclohexane. This successful company hoses the three largest cyclohexane plants in the world. Many are puzzled by how the production of cyclohexane seems to have become stagnant. Perhaps this is due to the cost of benzene increasing or the demand increasing. Through thorough investigation, the answer to this question and many more can be answered. There are two methods of obtaining cyclohexane. These two methods are fractional distillation of naphtha and hydrogenation of benzene. Research suggest that the hydrogenation of benzene is the most economical way to create our chemical of choice. According to ICIS, cyclohexane is used in the production of adipic acid used to …show more content…
Benzene, hydrogen and recycled cyclohexane with platinum catalyst contains low sulfur poisoning while nickel catalyst are permanently poisoned by sulfur.()Cyclohexane from petroleum is a complicated process which yields 85 wt. % purity. It is not a widely used method due to the close range of boiling points between byproducts dimethyl pentanes in natural cyclohexane concentrate. “It’s impractical to produce high purity yield.” () Physical and Chemical Properties Cyclohexane is a highly flammable liquid. It is colorless, mobile, water-insoluble, non-corrosive, easily vaporized and less toxic than benzene. Structurally it is a cycloparaffin and more times than not is in the Chair …show more content…
The crude oil is heated in a tall cylinder called fractionator for at least 350 degC. The process is based on the principle that different substances boil at different temperature. The cyclohexane content of naphtha fraction of crude oil can vary from 0.5 to 5.0 volume %. N-hexane, isohexanes, methyl cyclopentane, benzene and dimethyl pentanes have normal boiling points very close to cyclohexane.1 Advantages: 1. Uses a simple method of cyclohexane recovery. Disadvantages: 1. The fractions in the fractional distillation such as N-hexane, isohexane, methyl cyclopentane have normal boiling point close to cyclohexane which makes the recovery of cyclohexane uneconomic and difficult. 2. Quantity of cyclohexane recovered is not enough to meet the current demand since the cyclohexane content of naphtha is about 5%- 15% by weight .3 Selection of Pathway to Cyclohexane (2) Hydrogenation of Benzene: C6H6 +3H2 → C6H12 Possible side reactions: C6H6 + nH2 → cracking products C6H12 (benzene) ↔ C6H12 (methyl cyclo pentane) C6H6 + nH2 → C +
Feras Kaid Chem 2415-43 TA: Rio Assessment 1 Conclusion In this lab, there were 4 different distillations that were performed each with the same end goal to separate the two different organic compounds, cyclohexane and toluene. We used the boiling points of the two compounds to separate them using the following 4 techniques: microscale simple distillation, miniscale simple distillation, miniscale fractional packed distillation, and miniscale fractional unpacked distillation. The three different miniscale distillations were used to predict the accuracy of the distillation by comparing them to one other. The most accurate of the three distillations is the miniscale fractional packed distillation because this type uses a Vigreux column instead
One pair had a 50:50 mixture of cyclohexane: toluene while the other pair had a 50:50 mixture of cyclohexane: p-xylene. For both distillations, we were to collect the first milliliter and the last several drops in order to run a GC for each fraction. Furthermore, for both distillations, students obtained 30ml of their designated 50:50 mixture in a 50ml round bottom flask. By properly using the simple distillation apparatus, students were able to record the temperature of the distillate, we recorded the temperature for every 1ml. Once students collected the first 1ml, the 25ml of distillate and the remaining drops, we were able to determine the mole fraction of cyclohexane by using gas chromatography.
The purpose of this experiment was to separate all components in a mixture that was consisted of water, salt, sand and mineral oil. This was achieved through the knowledge on physical properties of the substances being used, and also through previous understanding of intermolecular forces. This lab is based on the Athabasca Oil Sands, which are located in Northern Alberta, an area that is highly controversial due to its negative impact on the environment and the First Nations People. In 2011, 52 million tons of crude oil were extracted and distilled for fossil fuels, making it one of the largest mining operations in the world. In this area, crude oil exists as bitumen, which is mixed with sediments like sand and clay.
Benzyne Formation and the Diels-Alder Reaction Preparation of 1,2,3,4 Tetraphenylnaphthalene Aubree Edwards Purpose: 1,2,3,4-tetraphenylnaphthalene is prepared by first producing benzyne via the unstable diazonium salt. Then tetraphenylcyclopentadienone and benzyne undergo a diels-alder reaction to create 1,2,3,4-tetraphenylnaphthalene. Reactions: Procedure: The reaction mixture was created. Tetraphenylcyclopentadienone (0.1197g, 0.3113 mmol) a black solid powder, anthranilic acid ( 0.0482g, 0.3516 mmol) a yellowish sand, and 1,2-dimethoxyethane (1.2 ml) was added to a 5-ml conical vial.
Referring to Table 1, the reactants for each run were transferred to an Erlenmeyer Flask (250 mL) via a buret. Using a precision pipette, the volume of I3- required for each run was carefully extracted and poured into the flask containing all of the reactants. Immediately after the Iodine solution was placed in the flask, the LabQuest began collection data. Meanwhile, a small portion of the solution, was used to rinse the cuvette, then using a disposable pipette a small amount of the solution was transferred to the cuvette (approx. ¾).
Fractional distillation was the better technique of separating toluene and cyclohexane than simple distillation because it had a greater percent toluene difference for fractions 2 and 4. Fraction 2 composed of mostly cyclohexane with a toluene percentage closer to 0% compared to simple distillation, while fraction 4 composed of mostly toluene with 100% toluene. The 100% toluene in fraction 4 indicated that the compound was purer in fractional distillation than in simple distillation, which had less percent
It is said that this fuel is dirty as well as the process that it will take to get this oil. This process would be harmful to people, wildlife as well as the environment. It has been stated that this process will inevitably leak,
Born on April 13, 1961 Robert William Fisher was born to a single mother in Brooklyn, New York. The struggles of a single parent caused Robert to experience a troubled childhood, which trickled over to his adulthood. Trying develop a better life for his family, he became a surgical technician, which paid for his schooling to become a respiratory therapist. Even with the support of his wife, life became difficult due to substance abuse. The drug of choice was crack cocaine, classified as a tertiary amine, which has three carbon atoms bonded directly to the nitrogen atom and general formula is R3N (Johll pg.
Water and Emission of Carmex Lip Care Raw Material Acquisition The Carmex is one of the oldest well-known lip care, lip balm company in United States, it offers lip balms in different proportions, such as in jars, tubes, and lip sticks. Carmex claimed that their “natural” lip balm formula helps remove cracked and peeling skin, and allow soothing and healing dry lip, and the menthol and camphor ingredients provide cool and refreshing tingle. The natural lip balm formula based on four main raw materials, which are Salicylic Acid, Phenol, Menthol and Camphor. Regarding to those four material, they are considered as hazardous materials, which are Eco-toxicity to human and to our environment.
Rediet Legese iLab Week # 6 CRUDE OIL DISTILLATION Introduction: The aim of this week lab experiment is to experiment distill crude oil and to check how temperature determine the chemical properties of crude oil plus how the boiling point can also show physical properties. They are two major finding in this experiment. he first finding was the point at which the raw petroleum is heated to the point of boiling, at 275 0C, the gas and kerosene oil are refined, however the oil (lubricant ) stays as an unrefined feature oil.
A sample of fish oil (50 mg) was transferred into screw-cap vial. 2 ml benzene and 10 ml sulfuric acid (1%) in absolute methanol were added. The vial was covered under a stream of nitrogen before heating in an oven 90 °C for 90 minutes. Ten ml of distilled water were added to the cooled vial and the methyl esters in each vial were extracted with 5 ml of petroleum ether for three times. The three petroleum ether extracts were combined and concentrate to its minimum volume by using a stream of nitrogen.
Bio-diesel production yields undesirable by-products for example methanol and glycerin. These by-products are removed so that the bio-diesel is suitable for use. Fractional distillation is used in the essential oil, flavor and fragrance industry. Raw essential oils are extracted from different plants such as mint, clove and tee tree for example. These raw oils contains impurities that have a bad flavour or odor.
Also, oxygenates are not present in naphtha from crude oil. The presence of oxygenates has been taken into account. However, details about the separation of oxygenates are beyond the scoop of this project. The requirement regarding the chain length is also important.
Petroleum refinery effluents (PRE) are wastes originating from industries engaged in refining crude oil and manufacturing lubricants, fuels and petrochemical intermediates. The effluents are composed of oil and grease along with many other toxic organic compounds and are a major source of aquatic environmental pollution. PRE can vary greatly depending on the plant configuration, the type of oil being processed, and operation procedures (Saien J. and Nejati H., 2007). The exact composition cannot be generalised as it depends on the refinery and which units are in operation at any specific time. PRE is often characterized by high concentrations of aliphatic and aromatic petroleum hydrocarbons, which usually have detrimental and harmful effects on plant and aquatic life
Nitroaromatic compounds are the major group of pollutants because they enter into environment in large quantities, are toxic and resistant to degradation and bioaccumulate. Nitroaromatics such as nitrobenzene, nitrotoluenes, nitrophenols, nitrobenzoates and nitroanilines are extensively used in industry for the manufacture of pesticides, explosives, dyes, plastics and pharmaceuticals. There are reports of widespread contamination of soil, water and atmosphere by nitroaromatic compounds. Nitrotoluenes are used in the large scale manufacture of explosives such as 2,4,6-trinitrotoluene (TNT), which has led to the contamination of soil. Environmental pollution by Nitroaromatic compounds Nitroaromatics are stable, persistent, toxic and mutagenic and many of them are suspected or recognized carcinogens (Lotufo et al., 2009; Marvin-Sikkema and de Bont 1994; Nishino et al., 2000; Padda et al., 2003; Purohit and Basu 2000; Reiger and Knackmuss 1995).