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Essential Reagents for Organic Chemistry: Exam 3 Guide
Essential Reagents for Organic Chemistry: Exam 3 Guide
School
Louisiana State University
*
*We aren't endorsed by this school
Course
CHEM 2261
Subject
Chemistry
Date
Dec 10, 2024
Pages
1
Uploaded by CommodoreMusic7702
List of Reagents Exam 3
HCl/ZnCl
2
(
or no
)
PCl
3
, PBr
3
, PI
3
, or SOCl
2
and
N
or pyr.
MsCl, TsCl or TfCl
and
N
or pyr.
H
2
SO
4
or H
3
PO
4
,
N
aH or
N
a
mCPBA
HCl
(1 equivalent)
HBr
(1 equivalent)
HCl (excess)
HBr (excess)
HBr, H
2
O
2
Cl
2
, CH
2
Cl
2
Br
2
, CH
2
Cl
2
Br
2
(excess), CH
2
Cl
2
Br
2
, H
2
O
Cl
2
(excess), CH
2
Cl
2
H
2
, Pd/C
H
2
(excess), Pd/C
H
2
,
N
i
H
2
(excess),
N
i
H
2
, Pt
H
2
(excess), Pt
H
2
O, H
2
SO
4
1) Hg(OAc)
2
/H
2
O (for ROH)
Hg(O
2
CCF
3
)
2
/ROH (for ROR)
2)
N
aBH
4
, OH
¯
1) BH
3
, THF
2) H
2
O
2
, H
2
O, OH
¯
ROH, H
2
SO
4
H
2
O, H
2
SO
4
, HgSO
4
1) R
2
BH (R=disiamyl)
2) H
2
O
2
, H
2
O, OH
¯
1)
N
a
N
H
2
2) RX
H
2
, Lindlar’s catalyst
N
a OR Li /
N
H
3
(liq)
78°C
KMnO
4
,
N
aOH, H
2
O
(cold)
1) OsO
4
, pyridine
2)
N
aHSO
3
, H
2
O
1)
KMnO
4
,
N
aOH,
H
2
O,
2)
H
3
O
+
1) O
3
2) (CH
3
)
2
S
or
Zn, H
2
O
1) O
3
2) H
2
O
1) LiAlH
4
, Et
2
O
2) H
2
O
H
2
CrO
4
, CrO
3
/H
2
SO
4
,
or
N
a
2
Cr
2
O
7
/H
2
SO
4
PCC
vincinal
geminal
111
insertion
Potter.hr
sn2
f
ePster
snzEl
EZOHTrandslkene
onffthestronaspor
alkene
epoxidie
marka.tk
11ggc
aaasagkytnalide
99
la
9bflideanti.mark
alkyl
vicinal
aerial
vicinal
abricixz
the
mmfee
EE
rma.nsBriitnal
I
fire
raise
cyanide
alkene
OH
Mark
rearrange
alkene
8
sides
noteartangement
alken
ketone
mark
alkene
on or
alkgtetmt.IE
ItIc
hsstoub
term
alkyne
ketone
Mark
Brene
yne
terminal
alkyne
aldehyde
alkyne
cis
alkene
yne
tread
Cleavage
ene
add20H
iboxylicacid
cleavage
meob
ff
adds
20H's
opposite
side
of
m
h
epoxide
alcohol
L
CH3x
1
alkyl
1
aci.ie
one10ROH
aldehyde
21181111
acid
2
rott
ketone
30
ROH
N.R
3
ROH
N.R