Linear Polyester Lab Report

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The two polyesters produced in the first part of this experiment are a linear structured polyester with thermoplastic properties, and a cross-linked polyester with thermosetting properties. The linear polyester was produced from the reaction of phthalic anhydride with ethylene glycol. Due to the fact that both of these components have only two functional groups, the polymer chain is linear. As shown in Picture 1 above, the product formed from the reaction is a solid and resulted in a dark color change. The solid structure is form after cooling and the color change represented the presence of a reaction. As shown in Table 1, the linear polymer was not brittle and was not viscous after cooling. The cross-linked polyester with thermosetting properties was produced from phthalic …show more content…

As shown in Table 1, Glyptal was a brittle product with some viscous liquid. In the second part of the experiment, the polyamide Nylon-6,6 was produced. There are two processes used to create high molecular weight polymers, step-growth and chain-growth. These two categories of polymerization can be used to produce nylons. Step-growth and chain-growth both begin with monomers which combine to form oligomers and then polymers. Unlike step-growth, the monomers in chain-growth do not exist as oligomers for a long period of time, but rather combine rapidly to form polymers. If a small molecule byproduct is produced along with the final product, then the polymerization is known as a polycondensation. If no byproduct is produced, then the polymerization is known as polyaddition. In this experiment, polyamide nylon-6,6 was produced and characterized as a step-growth polycondensation that produced water as a byproduct. In order to produce Nylon-6,6, hexamethylenediamine and adipoly chloride reacted in a solution of 20% sodium hydroxide. Adipoly chloride was used rather than dicarboxylic acid because it is more

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